1. stsadm -o enumservices > c:\services.txt - This will provide list of services
2. stsadm -o provisionservice -action stop -servicetype "Microsoft.Office.Server.Administration.ProfileSynchronizationService, Microsoft.Office.Server.UserProfiles, Version=14.0.0.0, Culture=neutral, PublicKeyToken=71e9bce111e9429c" -servicename FIMSynchronizationService
2. stsadm -o provisionservice -action stop -servicetype "Microsoft.Office.Server.Administration.ProfileSynchronizationService, Microsoft.Office.Server.UserProfiles, Version=14.0.0.0, Culture=neutral, PublicKeyToken=71e9bce111e9429c" -servicename FIMSynchronizationService